绿色缓蚀剂的研究进展及其在防腐涂层的应用

颜 　乐1, 陈财 洋*2, 刘 　伟2
1、沪东中华造船（集团）有限公司
2、厦门双瑞船舶涂料有限公司

摘要


绿色缓蚀剂所含有机化合物的极性基团能够与金属表面相互作用并形成缓蚀层，从而显著阻隔或减缓腐蚀
介质与金属持续接触，缓蚀剂可以与其他防腐技术相联合达到协同效果。因此，绿色缓蚀剂基于其协同缓蚀机制、
环境友好概念和缓蚀范围广成为了现下具有应用潜力的研究热点，结合近年来的绿色缓蚀剂的开发研究进展，总结
了缓蚀剂在自组装涂层技术以及智能防腐材料中的应用开发，分析石油化工、海洋工程等领域的绿色缓蚀剂自修复
涂层的应用前景。

关键词


绿色缓蚀剂；自组装涂层；智能缓蚀材料；工业腐蚀与防护

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参考


[1]Haruna K, Saleh T A, Obot I B, et al. Cyclodextrinbased functionalized grapheme oxide as an effective corrosion

inhibitor for carbon steel in acidic environment[J]. Progress in

Organic Coatings, 2019, 128: 157-167.

[2]Bashir S, Singh G, Kumar A. Shatavari (Asparagus

Racemosus) as Green Corrosion Inhibitor of Aluminium in

Acidic Medium[J]. Journal of Materials and Environmental

Sciences, 2017, 12(8): 84-91.

[3]刘云霞，文家新.绿色缓蚀剂对金属铝的缓蚀性

能研究进展[J].广州化工，2019，47（12）：27-28.

[4]Bashir S, Singh G, Kumar A. Shatavari (Asparagus

Racemosus) as Green Corrosion Inhibitor of Aluminium in

Acidic Medium[J]. Journal of Materials and Environmental

Sciences, 2017, 12(8): 84-91.

[5]Feng L, Zhang S T, Lu Y, et al. Synergistic corrosion

inhibition effect of thiazolyl-based ionicliquids between

anions and cations for copper in HCl solution[J]. Applied

Surface Science, 2019, 483: 901-911.

[6]Zhang K G, Yang W Z, Chen Y, et al. Enhanced

inhibitive performance of fluoro-substituted imidazoliumbased ionic liquid for mild steel corrosion in hydrochloric acid

at elevated temperature[J]. Journal of Materials Science, 2018,

53(20): 14666-14680.

[7]Cao S Y, Liu D, Zhang P, et al. Green Brönsted acid

ionic liquids as novel corrosion inhibitors for carbon steel in

acidic medium[J]. Scientific Reports, 2017,7(1): 1-14.

[8]Wei Z F, Chen X, Duan J, et al. Branched chain

versus straight chain fluorinated surfactant: A comparative

study of their anticorrosion performance on carbon steel[J].

Journal of molecular liquids, 2019, 280: 327-333.

[9]Nuer M, Duan J, Wei Z, et al. Fluorocarbonhydrocarbon hybrid cationic surfactants: Synthesis, surfaceactivity properties and anti-corrosion performance[J]. Journal

of Molecular Liquids, 2020, 306: 112897.

[10]M. EHTESHAMZADE, T. SHAHRABI, M.G.

HOSSEINI. Inhibition of copper corrosion by self-assembled

films of new Schiff bases and their modification with alkanethiols

in aqueous medium[J]. Applied Surface Science: A Journal

Devoted to the Properties of Interfaces in Relation to the

Synthesis and Behaviour of Materials,2006,252(8):2949-2959.

[11]张镇川，陈友媛，宋芳，等.植酸对咸水介质中

316L不锈钢耐蚀性的影响[J].材料导报，2016，30（6）：

106-110，140.

[ 1 2 ] Z H A O , W E I J I E , G O T H E L I D , M A T S ,

HOSSEINPOUR, SAMAN, et al. The nature of selfassembled octadecylphosphonic acid (ODPA) layers on

copper substrates[J]. Journal of Colloid and Interface

Science,2021,581(Pt.B):816-825.

[13]HU, YONGMAO, LI, RUHENG, ZHANG,

XUEQING, et al. Aluminium films roughened by hot water

treatment and derivatized by fluoroalkyl phosphonic acid:

wettability studies[J]. Surface Engineering,2020,36(5/6):589-600.

[14]郭孟莹.自修复涂料用微胶囊的制备及性能表征

[D].黑龙江：哈尔滨工程大学，2018.

[15]莫师.铜的防腐蚀技术：香料类绿色缓蚀剂及

pH刺激响应型自修复涂层[D].重庆：西南大学，2017.

[16]IZADI, M., SHAHRABI, T., RAMEZANZADEH,

B.. Synthesis and characterization of an advanced layer-bylayer assembled Fe3O4/polyaniline nanoreservoir filled with

Nettle extract as a green corrosion protective system[J]. Journal

of industrial and engineering chemistry,2018,57263-274.

[17]Luo Xiaohu, Pan Xinyu, Yuan Song, Du Shuo, Liu

Yali*. Corrosion inhibition of mild steel in simulated seawater

solution by a green eco-friendly mixture of glucomannan

(GL) and bisquaternary ammonium salt (BQAS). Corrosion

Science, 2017, 125: 139-151.

[18]李俐枝，彭云超，李丰渟，等.哌嗪类曼尼希

碱壳聚糖缓蚀剂的制备及缓蚀性能研究[J].表面技术，

2022，51（5）：139-147，157.

[19]魏 佳 煜， 邱 诗 惠， 赵 海 超， 等.聚 左 旋 多

巴-SiO2复合材料在1MHCl中的缓蚀作用[J].中国表面工

程，2022，35（2）：55-62.

[20]Elshafe A. Gad·Ashraf M. El‑Shamy, Mechanism

of Corrosion and Microbial Corrosion of 1,3-Dibutyl

Thiourea Using the Quantum Chemical Calculations Journal

of Bio-andTribo-Corrosion,2198-4220, Volume 8, Issue 3,

2022, Pages 1-12.




DOI: http://dx.doi.org/10.12361/2661-3786-06-05-135689

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